Preparation of surface imprinted material of single enantiomer of mandelic acid with a new surface imprinting technique and study on its chiral recognition and resolution properties
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- 作者：Baojiao Gao ; gaobaojiao@126.com" class="auth_mail" title="E-mail the corresponding author ; Lulu Chen chenlulu@163.com" class="auth_mail" title="E-mail the corresponding author ; Yanbin Li liyanbin@126.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Mandelic acid ; Hydroxyethyl methylacrylate ; Molecule surface imprinting ; Chiral recognition ; Chiral resolution
- 刊名：Journal of Chromatography A
- 出版年：2016
- 出版时间：22 April 2016
- 年：2016
- 卷：1443
- 期：Complete
- 页码：10-20
- 全文大小：2559 K
文摘
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A surface initiating system of −SH/BPO was constituted on interface of SiO2 particles and solution.
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A new surface imprinting method of synchronously graft-polymerizing and imprinting was utilized.
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A surface imprinted material of the single enantiomer of mandelic acid was successfully prepared.
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(R)-Mandelic acid imprinted material has excellent enantiomeric recognition ability.
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This (R)-enantiomer imprinted material has good chiral resolution ability for raceme.