Simple fabrication of highly dispersive β-Si3N4 seeds with moderate aspect ratio
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- 作者：Xiuan Xi ; xixiuan@163.com ; Hao Xiong ; Junjie Yu ; Weiming Guo ; guo1237@126.com ; Hua-Tay Lin
- 关键词：Silicon nitride ; Rod-like seed ; Aspect ratio ; Acid treatment ; Distribution
- 刊名：Ceramics International
- 出版年：2017
- 出版时间：1 February 2017
- 年：2017
- 卷：43
- 期：2
- 页码：2888-2891
- 全文大小：920 K
- 卷排序：43
文摘
A powder mixture was prepared using α-phase-rich silicon nitride (Si3N4) as the major raw material, with 0.5 wt% Yb2O3 as the additive. These powders were fired at 1650–1800 °C for 0.5–2 h at a nitrogen pressure of 0.1 MPa. The effects of firing temperature and holding time on the crystalline phase and microstructure evolution of β-Si3N4 seeds were investigated in detail. The particle size distribution of the β-Si3N4 seeds before and after acid treatment was also evaluated using laser diffraction/scattering. The results show that, even with a low mass fraction of sintering additive, rod-like β-Si3N4 seeds with an average aspect ratio of ~4 could be successfully obtained after firing at 1750 °C for 2 h. Furthermore, the use of a dilute HF soak for a short period, the resultant powder showed a single peak frequency distribution with a narrow particle size range (D50≈2.5 µm). This suggests that the residual crystalline/glassy phase contained in the as-prepared powder is readily attacked by acid rinse, resulting in the subsequent easy separation of the β-Si3N4 seed grains. The present method is therefore a simple and promising procedure for the preparation of highly dispersive rod-like β-Si3N4 seeds for use in the mechanical properties improvement of Si3N4 ceramics.