Mechanisms of alkane CH-activation: The 5/6 effect, single-factor compensation effect, strongest reactant and earliest transition state. A puzzle of Shilov reaction

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• 作者：Elisey S. Rudakov ^{rudakove@ukr.net}
• 关键词：Alkane CH-activation ; Functionalization of CH bond ; Kinetics ; 5/6 effect ; Single-factor compensation effect ; Shilov chemistry
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PB
• 页码：465-473
• 全文大小：2982 K
• 卷排序：426

文摘

Direct kinetic study of alkane activation and the 5/6 effect allowed to establish mechanisms of CH bonds cleavage. Reactions with metal complexes and other reactants were investigated. A theory of the compensation effects was developed. Acido complexes of HgII, PdII and PtII in the alkane activation do not differ from other reactants.