Dipyrrolidinomethylaminophosphoric acid triamide (DPMPA) as an activator for the samarium diiodide-mediated reduction of alkyl and aryl halides

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• 作者：Chriss E. McDonald ; ^{mcdonald@lycoming.edu} ; Jeremy R. Ramsey ; David G. Sampsell ; Laura A. Anderson ; Jordan E. Krebs ; Samantha N. Smith
• 刊名：Tetrahedron
• 出版年：2013
• 出版时间：8 April, 2013
• 年：2013
• 卷：69
• 期：14
• 页码：2947-2953
• 全文大小：923 K

文摘

The use of the conjugate base of dipyrrolidinomethylaminophosphoric triamide (DPMPA^?) as an activator of samarium diiodide is reported. This phosphoramidate has been shown to be a very potent ligand, allowing for the efficient, low-temperature reduction of alkyl and aryl chlorides. Reductive cyclizations of haloalkenylnaphthalenes are also reported.