Roles of water and dissolved oxygen in photocatalytic generation of free OH radicals in aqueous TiO2 suspensions: An isotope labeling study
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文摘

Origin of free <font color=radical dot" data-inlimg="/entities/rad" src="/sd/grey_pxl.gif" class="glyphImg imgLazyJSB">OH in aqueous TiO2 photocatalysis was studied by isotope labeling.

Influence of hole and electron scavengers on generation of free <font color=radical dot" data-inlimg="/entities/rad" src="/sd/grey_pxl.gif" class="glyphImg imgLazyJSB">OH was explored.

Hole-driven oxidation of H2O is the main source of free <font color=radical dot" data-inlimg="/entities/rad" src="/sd/grey_pxl.gif" class="glyphImg imgLazyJSB">OH.

Reduction of dissolved O2 plays a minor role in formation of free <font color=radical dot" data-inlimg="/entities/rad" src="/sd/grey_pxl.gif" class="glyphImg imgLazyJSB">OH.

Amounts of free <font color=radical dot" data-inlimg="/entities/rad" src="/sd/grey_pxl.gif" class="glyphImg imgLazyJSB">OH were estimated using remote degradation of a probe compound.

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