Syntheses, structural variations and fluorescence studies of two dinuclear zinc(II) complexes of a Schiff base ligand with an extended carboxylate side arm
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- 作者：Shyamapada Shita ; b ; Ashok Sasmala ; d ; Piu Dhala ; Corrado Rizzolic ; Samiran Mitraa ; smitra_2002@yahoo.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Zinc(II)-Schiff base complexes ; Characterization ; μ1 ; 3- and μ1 ; 1-carboxylato-bridges ; Fluorescence
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：15 March 2016
- 年：2016
- 卷：1108
- 期：Complete
- 页码：475-481
- 全文大小：1295 K
文摘
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Two dinuclear zinc(II)-Schiff base complexes were synthesized.
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Characterized by spectroscopic and crystallographic methods.
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Nuclearity of the complexes influenced by chlorine present in ligand backbone.
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Steric effect of counter ions controls the ligating properties of carboxylate group.
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Fluorescence studies suggest photoactive properties of the complexes.