Contemplation on spark sensitivity of certain nitramine type explosives

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• 作者：Lemi Tü ; rker
• 关键词：Spark sensitivity ; Explosives ; Nitro compounds ; Nitramines
• 刊名：Journal of Hazardous Materials
• 出版年：2009
• 出版时间：30 September 2009
• 年：2009
• 卷：169
• 期：1-3
• 页码：454-459
• 全文大小：307 K

文摘

Spark sensitivity of explosives is an important subject. Presently, some correlations are sought between the spark sensitivity and certain molecular orbital characteristics of some nitramine type explosives. For that purpose certain semi-empirical and DFT calculations have been carried out. Investigations have revealed that the nitramines considered undergo decomposition in the electric field mainly via their anionic states.