Quasi-bound complexes in collisions of different linear molecules: Classical trajectory study of their manifestations in rotational relaxation and spectral line broadening
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- 作者：Sergey V. Ivanov serg.ivanov.home@mail.ru" class="auth_mail" title="E-mail the corresponding author
- 关键词：Collision complexes ; Classical trajectories ; Spectroscopic manifestations
- 刊名：Journal of Quantitative Spectroscopy and Radiative Transfer
- 出版年：2016
- 出版时间：July 2016
- 年：2016
- 卷：177
- 期：Complete
- 页码：269-282
- 全文大小：1703 K
文摘
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Principal difference between classical "orbitings" and quaibound complexes (QCs).
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Fractions of QCs in binary collisions of different linear molecules as a function of rotational quantum number.
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Influence of QCs on rotational R-T relaxation and vibration–rotational spectral line broadening; explicit formulae presented.
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Importance of including QCs in any theoretical modeling of spectroscopic manifestation of intermolecular interactions.
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Possible manifestation of non-impact effects in central regions of spectral lines due to QCs.