A 6 Ma chemical weathering history, the grain size dependence of chemical weathering intensity, and its implications for provenance change of the Chinese loess–red clay deposit

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• 作者：Shangfa Xiong ; Zhongli Ding ; Yuanjian Zhu ; Ru Zhou ; Haijian Lu
• 刊名：Quaternary Science Reviews
• 出版年：2010
• 出版时间：July 2010
• 年：2010
• 卷：29
• 期：15-16
• 页码：1911-1922
• 全文大小：2576 K

文摘

Major element chemical analyses of the Baishui loess–red clay sequence (35° 24′ 10″N, 106° 54′ 43″E, Gansu Province, China) reveal that, the chemical weathering intensities inferred from CIA (chemical index of alteration) values have progressively weakened and increased in amplitude with decreasing age. The general trend of the CIA can be correlated well with the oxygen isotope variations of the deep sea sediments. Analyses of multiple size fractions (<5 μm, 5–20 μm and 20–63 μm) indicate that the CIA and the major element abundances are strongly grain size dependent. The chemical alternation of all three size fractions is relatively weak, and the long-term variation in chemical composition of the loess–red clay is mainly controlled by the mixing of fresh detritus from different source areas. The CIA variability of the coarse fractions (5–20 μm and 20–63 μm) within the section is apparently different from that of the fine fraction (<5 μm), implying a different erosion–transportation–deposition–weathering history. From 1 Ma onward, CIA values for all size fractions decrease, indicating an increasing input of fresh or poorly weathered detritus in the desert source regions of loess deposits. Sequential variations in the K₂O/Al₂O₃, Na₂O/Al₂O₃, CaO/Al₂O₃ and MgO/Al₂O₃ ratios from 4.5 Ma to about 0.6 Ma in bulk and size fractioned samples may reflect provenance change as well as changing chemical weathering processes.