Mesoporous ¦Á-Ni(OH)2 was synthesized by a facile method and investigated as an electrochemical pseudocapacitor material. Structural characterizations reveal that the mesoporous ¦Á-Ni(OH)2 has a narrow pore size distribution of 16 nm and a large surface area of 349 m2 g?#xA0;1. The ¦Á-Ni(OH)2 sample exhibits excellent electrochemical performance at different current densities and good cycling ability, which can be due to its mesoporous structure and large surface area. A maximum specific capacitance of 1718 F g?#xA0;1 can be achieved at a scan rate of 5 mV s?#xA0;1. These results indicate that the mesoporous ¦Á-Ni(OH)2 is a promising candidate for the supercapacitor electrodes.