Polymeric membrane formation by wet-phase separation; turbidity and shrinkage phenomena as evidence for the elementary processes
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- 作者：Stropnik ; C. ; Musil ; V. ; Brumen ; M.
- 关键词：Mechanisms of membrane formation by wet-phase separation ; Elementary processes ; Turbidity
- 刊名：Polymer
- 出版年：2000
- 出版时间：December 15, 2000
- 年：2000
- 卷：41
- 期：2
- 页码：9227-9237
- 全文大小：236 K
文摘
The direct accumulation of polymer, the nucleation and growth of the polymer lean as well as the polymer rich phase and the spinodal phase separation are postulated as four elementary processes of the mechanisms of the polymeric membrane formation by wet-phase separation. With the study of five different polymer/solvent:water systems they are discriminated by the investigation of the turbidity and the shrinkage phenomena taking place during (proto)membrane formation, as well as by the measurement of the pure water permeability and by the inspection of the membranes’ cross-section morphology. The general scheme of membrane formation mechanisms is arranged by gathering the groups of different modes of mass transport and the group of nonsolvent/solvent/polymer forms of solidification as elementary processes; by forming combinations of the so postulated elementary processes in time and space particular mechanisms are established.