Concentration-dependent structure and dynamics of aqueous LiCl solutions: A molecular dynamics study

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• 作者：Saurav Prasad ; Charusita Chakravarty ; Hemant K. Kashyap ; ^{hkashyap@chemistry.iitd.ac.in}
• 关键词：alkali halides ; terahedral order ; triplet correlation functions
• 刊名：Journal of Molecular Liquids
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：225
• 期：Complete
• 页码：240-250
• 全文大小：997 K
• 卷排序：225

文摘

Rosenfeld scaling holds true for aqueous LiCl solutions. Aqueous LiCl solutions display fractional Stokes-Einstein relation. Ionic conductivity shows a non-monotonic dependence on LiCl concentration. Negative deviation from Nernst-Einstein relation is notable in glass-forming regime.