Copper(II) coordination chain complexes with the 3,5-diacetyl-4-methylpyrazole dioxime ligand: Synthesis, crystal structures and magnetic properties
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- 作者：Moha Outiritea ; b ; Bouchaib Mernaric ; Fouad Bentissc ; Frederic Capeta ; Michel Lagrené ; ea ; michel.lagrenee@ensc-lille.fr
- 关键词：Copper(II) complexes ; Oxime ; Zwitterion structure ; 1D chain ; X-ray ; Magnetic measurements
- 刊名：Journal of Molecular Structure
- 出版年：2011
- 出版时间：15 March 2011
- 年：2011
- 卷：989
- 期：1-3
- 页码：60-69
- 全文大小：2317 K
文摘
3,5-Diacetyl-4-methylpyrazole dioxime (dampdoH3) has been found to form with copper(II), in the presence of different anions (perchlorate, nitrate, triflate and tetrafluoroborate), four new dimeric complexes, [Cu2(dampdoH2)2(ClO4)2] (1); [Cu2(dampdoH2)2(H2O)2]2NO3 (2); [Cu2(dampdoH2)2(CF3SO3)2] (3) and [Cu2(dampdoH2)2(BF4)2] (4). The molecular structure of [Cu2(dampdoH3)2]2+ which is the common unit for the four complexes is composed of binuclear species where one of the oxime functions has the classical structure while the second function has a zwitterionic structure. For the four complexes these binuclear units are parallel and are bound together by a strong intermolecular bond to create an infinite 1D chain expanding along the crystallographic “a” axis. Variable-temperature magnetic susceptibility measurements for complex 1 indicate a very strong antiferromagnetic exchange coupling intra or/and interdimeric ring, the J1 value of the intradimer coupling being strongest than the interbinuclear coupling J2 (J1 = −346 cm−1, J2 = −119.15 cm−1).