Study of molecular interactions of binary mixtures DEC with alkoxyalkanols at various temperatures

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• 作者：M. Srilakshmi^a ; T. Srinivasa Krishna^b ; ^{sritadikonda@gmail.com} ; K. Narendra^c ; Ch. Kavitha^a ; A. Ratnakar^a
• 关键词：Diethyl carbonate (DEC) ; 2-Alkoxyethanols ; Density ; Speed of sound ; Refractive index ; Inter molecular interactions
• 刊名：The Journal of Chemical Thermodynamics
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：105
• 期：Complete
• 页码：452-468
• 全文大小：1823 K
• 卷排序：105

文摘

ρ, u and nD was measured of DEC with 2-alkoxyethanols between 298.15–323.15 K. Excess thermodynamic parameters were calculated and correlated with R–K polynomial. Results were interpreted in terms of intermolecular interactions. The effects of temperature and concentration on ρ, u and nD were discussed.