BODIPY photocatalyzed oxidation of thioanisole under visible light

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• 作者：Wenliang Li^a ;   ; ^b ; Zhigang Xie^a ;   ; ^{xiez@ciac.jl.cn} ; Xiabin Jing^a
• 关键词：Photocatalysis ; Bodipy ; Thioanisole ; Photo-oxidation
• 刊名：Catalysis Communications
• 出版年：2011
• 出版时间：30 November 2011
• 年：2011
• 卷：16
• 期：1
• 页码：94-97
• 全文大小：844 K

文摘

4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes are organic dyes which have excellent thermal and photochemical stability, high fluorescence quantum yield and good solubility. Four BODIPY dyes were made and used to investigate the oxidation of thioanisole under visible light. BODIPY dyes were shown to be highly active photocatalysts which are comparable to the metal complex, like Ru(bpy)₃²⁺. This work highlights the potential of using BODIPY as photocatalysts for a number of important organic transformations.