Synthesis and reactivity of di- and tri-metallic complexes containing the TpRu(PPh3) fragment
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- 作者：Li-Sheng Hsu ; Yih-Hsing Lo ; yhlo@utaipei.edu.tw" class="auth_mail" title="E-mail the corresponding author
- 关键词：Tris(pyrazolyl)borato ; Ruthenium ; Vinylidene ; Alkenyl ketone ; Ferrocene
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 June 2016
- 年：2016
- 卷：812
- 期：Complete
- 页码：177-182
- 全文大小：632 K
文摘
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We reported new method for synthesis of di and tri-metallic complexes.
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Reaction of TpRu complex with ethynylferrocene in MeOH was studied.
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A number of new cationic vinylidene complexes have been prepared.
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Their structures are elucidated by IR, NMR and X-ray crystallography.