Comparison of the photoelectrochemical performance of particulate and nanotube TiO<sub>2sub> photoanodes
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Double layer capacitance can estimate the relative surface area of photoanodes.

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The R<sub>ctsub>Q<sub>dlsub> product is a measure of intrinsic photoelectrocatalytic activity.

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TiO<sub>2sub> nanotubes show lower intrinsic photoactivity compared to TiO<sub>2sub> sol-gel.

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Higher surface area of TiO<sub>2sub> nanotubes enhances photocurrent and degradation rates.

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