Ligand 4-X pyridine (X p>= p>Cl, Br, I) dependence in Hofmann-type spin crossover complexes: Fe(4-Xpyridine)2[Au(CN)2]2
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- 作者：Jun Okabayashi
- 关键词：Spin crossover complexes ; X-ray absorption fine structure ; Fe&ndash ; Au complexes ; Aurophilic interaction
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：24 April 2016
- 年：2016
- 卷：445
- 期：Complete
- 页码：17-21
- 全文大小：688 K
文摘
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- <p id="p0005">Novel spin crossover complexes Fe(4-Xpy)2[Au(CN)2]2 with axial 4-X pyridine ligands (X = Cl, Br, and I).p>
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- <p id="p0010">The halogen-element dependence in the lattice parameters on the magnetic properties.p>
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- <p id="p0015">Structure parameters determined by EXAFS of Fe K edge and Au Ledge.p>
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- <p id="p0020">Aurophilic interaction studied.p>