Mixed anion effect was used to improve electrochemical properties of Lib>3b>Feb>2b>(POb>4b>)b>3b>.
The VOb>4b>3− substitution improved rate capability and cyclability of Lib>3b>Feb>2b>(POb>4b>)b>3b>.
The Lib>3b>Feb>2b>(POb>4b>)b>2.55b>(VOb>4b>)b>0.45b> material shows the excellent electrochemical performance.
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