Synthesis and properties of tricarbazole-functionalized poly(norbornene-dicarboximide)
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- 作者：Jianhua Wu ; Yanbin Fu ; Wenmei Liu ; Xiaojuan Liao ; Meiran Xie ; mrxie@chem.ecnu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Ruyi Sun ; rysun@chem.ecnu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ring-opening metathesis polymerization ; Polynorbornene ; Tricarbazole ; Properties
- 刊名：European Polymer Journal
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：76
- 期：Complete
- 页码：110-121
- 全文大小：912 K
文摘
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A series of poly(norbornene-dicarboximide)s were synthesized by ROMP.
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Introducing various acceptors to tricarbazole can achieve different color emission.
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The HOMO levels of polymers are close to the most common hole injection materials.
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The LUMO level of polymer with the cyano group is very close to the material of Alq3.
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Polymers possess high thermal stability with decomposition temperature over 400 °C.