Fluorescent (pyrazolyl acetoxime)Zn^II complexes: Synthetic, structural, and photophysical studies

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• 作者：Dmitrii S. Bolotin^a ; ^{dmitriy.s.bolotin@gmail.com} ; Mikhail V. Il&rsquo ; in^a ; Ilya E. Kolesnikov^b ; Vitaliy V. Suslonov^c ; Yuri Novozhilov^d ; Oksana Ronzhina^d ; Mikhail Krasavin^a ; Vadim P. Boyarskiy^a ; Renier Koen^e ; Andreas Roodt^e
• 关键词：Fluorescence ; Pyrazole ; Oxime ; Zinc complex
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P1
• 页码：9-14
• 全文大小：986 K
• 卷排序：455

文摘

Pyrazolyl acetoxime zinc complexes exhibit fluorescence with maxima at 460–509 nm. Substituents in the pyrazolyl acetoxime ligands vary emission maxima for ca. 50 nm. The substituents substantially affect the quantum yield with 37-fold variation.