Solvent-free synthesis of alkyl and fluoroalkyl sulfonium salts from sulfides and fluoroalkyl trifluoromethanesulfonates

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• 作者：Hai-Xia Song ; Shi-Meng Wang ; Xiao-Yan Wang ; Jia-Bin Han ; Ying Gao ; Su-Jiao Jia ; Cheng-Pan Zhang ; ^{cpzhang@whut.edu.cn} ; ^{zhangchengpan1982@hotmail.com}
• 关键词：Sulfides ; Fluoroalkyl trifluoromethanesulfonates ; Sulfonium salts
• 刊名：Journal of Fluorine Chemistry
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：192
• 期：part_PA
• 页码：131-140
• 全文大小：913 K
• 卷排序：192

文摘

Solvent-free facile synthesis of alkyl and fluoroalkyl sulfonium salts. Fluoroalkyl trifluoromethanesulfonates were used as fluoroalkyl sources. The reaction could selectively afford alkyl- or fluoroalkylsulfonium salts. The reactants and reaction temperature dramatically affected the reaction.