Hydrogenation of olefins using Hantzsch ester catalyzed by palladium on carbon

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• 作者：Qiang Liu ; Jing Li ; Xiao-Xia Shen ; Rui-Guang Xing ; Jie Yang ; Zhengang Liu ; Bo Zhou
• 关键词：Olefins ; α ; β ; -Unsaturated ketones ; Hantzsch ester ; Palladium on carbon ; Hydrogenation ; Reduction
• 刊名：Tetrahedron Letters
• 出版年：2009
• 出版时间：4 March 2009
• 年：2009
• 卷：50
• 期：9
• 页码：1026-1028
• 全文大小：163 K

文摘

Hantzsch 1,4-dihydropyridine (HEH), a well-known model compound of coenzyme NAD(P)H was found as an efficient reducing agent in hydrogenation of unactivated olefins catalyzed by Pd/C. α,β-Unsaturated ketones also underwent hydrogenation, affording the corresponding saturated ketones selectively.