Thiourea binding with carboxylic acid promoted cationic ring-opening polymerization
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- 作者：Xiaopei Li ; Qiguo Zhang ; Zhenjiang Li ; Xin Wang ; Jingjing Liu ; Saide Cui ; Songquan Xu ; Chengxu Zhao ; Cheng Chen ; Kai Guo ; guok@njtech.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ring-opening polymerization ; Brø ; nsted acid ; Hydrogen bonding
- 刊名：Polymer
- 出版年：2016
- 出版时间：10 February 2016
- 年：2016
- 卷：84
- 期：Complete
- 页码：293-303
- 全文大小：2599 K
文摘
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A new protocol of hydrogen bond donor binding with Brønsted acid (HBD–BA) catalysis in polymerization.
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Thiourea and trifluoroacetic acid (TU-TFA) as a model co-catalysts promoted ROPs of δ-VL and ε-CL successfully.
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HBD–BA catalyzed polymerization was in controlled/living nature.