One-Dimensional Metal-Organic Framework with Unprecedented Heptanuclear Copper Units
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- 作者：Sacramento Ferrer ; Elena Aznar ; Francesc Lloret ; Alfonso Castiñ ; eiras ; Malva Liu-Gonzá ; lez ; Joaquí ; n Borrá ; s
- 刊名：Inorganic Chemistry
- 出版年：2007
- 出版时间：January 22, 2007
- 年：2007
- 卷：46
- 期：2
- 页码：372 - 374
- 全文大小：103K
- 年卷期：v.46,no.2(January 22, 2007)
- ISSN：1520-510X
文摘
The reaction of copper(II) sulfate, copper(II) chloride, 3,5-diacetylamino-1,2,4-triazole, and 3-acetylamino-5-amino-1,2,4-triazole in water yields green, plate-shaped crystals of [[{Cu3(
ntities/mgr.gif">3-OH1/2)L(H2O)2Cl}2{ntities/mgr.gif">-Cu(H2O)2Cl2}]·12H2O]n (1), where L is a newtriazole-derived macrocyclic ligand. The structure of 1 consists ofheptanuclear (H)OCuII3-CuII-CuII3O(H) entities linked in pairsthrough symmetric ntities/mgr.gif">3-O···H···O-ntities/mgr.gif">3 hydrogen bonds to form adouble-stranded one-dimensional network. A significant overallantiferromagnetic behavior has been observed for 1.
ntities/mgr.gif">3-OH1/2)L(H2O)2Cl}2{ntities/mgr.gif">-Cu(H2O)2Cl2}]·12H2O]n (1), where L is a newtriazole-derived macrocyclic ligand. The structure of 1 consists ofheptanuclear (H)OCuII3-CuII-CuII3O(H) entities linked in pairsthrough symmetric ntities/mgr.gif">3-O···H···O-ntities/mgr.gif">3 hydrogen bonds to form adouble-stranded one-dimensional network. A significant overallantiferromagnetic behavior has been observed for 1.