An Electroactive Dynamically Polydisperse Supramolecular Dendrimer

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• 作者：Gustavo Fern&aacute ; ndez ; Emilio M. Pé ; rez ; Luis S&aacute ; nchez ; Nazario Martí ; n
• 刊名：Journal of the American Chemical Society
• 出版年：2008
• 出版时间：February 27, 2008
• 年：2008
• 卷：130
• 期：8
• 页码：2410 - 2411
• 全文大小：143K
• 年卷期：v.130,no.8(February 27, 2008)
• ISSN：1520-5126

文摘

We describe the synthesis and supramolecular properties of a bifurcated molecule decorated with two units of an in-house receptor for [60]fullerene, based on the electron donor exTTF, and a PC₆₁BA derivative as recognizing units. This monomer self-assembles to form arborescent and dynamically polydisperse supramolecular aggregates, mainly through s/gifchars/pi.gif" BORDER=0 >-s/gifchars/pi.gif" BORDER=0 > interactions. This constitutes a fundamentally novel kind of organization of electroactive materials that lies at the interface between dendrimers and supramolecular polymers.