SRC="/isubscribe/journals/orlef7/10/i06/figures/ol800161mn00001.gif" ALIGN="left" HSPACE=5> |
A
straightforward and high-yielding acce
ss to variou
s [2.2]paracyclophane
s po
sse
ssing a
sulfur-ba
sed functional group i
s reported, the key
step being a S
EAr reaction mediated by a
sulfonium
salt. The ver
satility of the methodology wa
s exemplified by an original application in
sulfenate
salt chemi
stry, from which a remarkable chirality tran
sfer wa
s ob
served.