Oxazolinyl-Assisted C–H Amidation by Cobalt(III) Catalysis

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• 作者：Ruhuai Mei ; Joachim Loup ; Lutz Ackermann
• 刊名：ACS Catalysis
• 出版年：2016
• 出版时间：February 5, 2016
• 年：2016
• 卷：6
• 期：2
• 页码：793-797
• 全文大小：491K
• ISSN：2155-5435

文摘

Cobalt-catalyzed C–H activation by means of oxazolinyl assistance set the stage for versatile direct amidations with ample substrate scope. Thus, a high-valent cobalt(III) catalyst enabled C–H amidations with excellent levels of positional and chemo-selectivities. Mechanistic studies provided strong support for a kinetically relevant C–H functionalization.