Hybrid Rylene Arrays via Combination of Stille Coupling and C鈥揌 Transformation as High-Performance Electron Transport Materials
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- 作者：Wan Yue ; Aifeng Lv ; Jing Gao ; Wei Jiang ; Linxiao Hao ; Cheng Li ; Yan Li ; Lauren E. Polander ; Stephen Barlow ; Wenping Hu ; Simone Di Motta ; Fabrizia Negri ; Seth R. Marder ; Zhaohui Wang
- 刊名：The Journal of the American Chemical Society
- 出版年：2012
- 出版时间：April 4, 2012
- 年：2012
- 卷：134
- 期：13
- 页码：5770-5773
- 全文大小：281K
- 年卷期：v.134,no.13(April 4, 2012)
- ISSN：1520-5126
文摘
Hybrid rylene arrays have been prepared via a combination of Stille coupling and C鈥揌 transformation. The ability to extend the 蟺 system along the equatorial axis of rylenes not only leads to broadened light absorption but also increases the electron affinity, which can facilitate electron injection and transport with ambient stability.