Transition-Metal-Free Synthesis of Fluorinated Arenes from Perfluorinated Arenes Coupled with Grignard Reagents

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• 作者：Yunqiang Sun ; Hongjian Sun ; Jiong Jia ; Aiqin Du ; Xiaoyan Li
• 刊名：Organometallics
• 出版年：2014
• 出版时间：February 24, 2014
• 年：2014
• 卷：33
• 期：4
• 页码：1079-1081
• 全文大小：207K
• 年卷期：v.33,no.4(February 24, 2014)
• ISSN：1520-6041

文摘

A simple method to obtain organofluorine compounds from perfluorinated arenes coupled with Grignard reagents in the absence of a transition-metal catalyst was reported. In particular, the perfluorinated arenes could react not only with aryl Grignard reagents but also with alkyl Grignard reagents in moderate to good yields.