The suspended particles of an electrorheological (ER) fluid can be easily arrayed as a crystallite of abody-centered tetragonal (bct) lattice structure using an external electric field. Thus the entropy of thisprocess, which is generally recognized as a first-order phase transition, would greatly decrease. From thisfact, we theoretically derive that the dielectric loss tangent maximum value of the dispersed particlesshould be larger than 0.1, which agrees well with the currently observed experimental results; the negativeER effect becomes possible only when d
sp/d
T < 0, where
sp is the static dielectric constant of the dispersedparticle material and
T is temperature.