Anionic Guests in Prismatic Cavities Generated by Enneanuclear Nickel Metallacycles
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- 作者：Jordi Esteban ; Mercè Font-Bardia ; Albert Escuer
- 刊名：Inorganic Chemistry
- 出版年：2014
- 出版时间：January 21, 2014
- 年：2014
- 卷：53
- 期：2
- 页码：1113-1121
- 全文大小：518K
- ISSN：1520-510X
文摘
The combination of polydentate aminated ligands with the 2-pyridyloxime-nickel-azide system leads to series of clusters with unprecedented topologies. Among them, a remarkable family of {Ni9} metallacycles that are capable of selective encapsulation of azide/halide anions in a cryptand-like cavity through hydrogen-bond interactions has been characterized.