Slow Magnetization Relaxation in Unprecedented MnIII4DyIII3 and MnIII4DyIII5 Clusters from the Use of N-S

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• 作者：Dimitris I. Alexandropoulos ; Tu N. Nguyen ; Lu铆s Cunha-Silva ; Theodoros F. Zafiropoulos ; Albert Escuer ; George Christou ; Theocharis C. Stamatatos
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：February 4, 2013
• 年：2013
• 卷：52
• 期：3
• 页码：1179-1181
• 全文大小：240K
• 年卷期：v.52,no.3(February 4, 2013)
• ISSN：1520-510X

文摘

The first use of N-salicylidene-o-aminophenol in 3d/4f chemistry has led to Mn^III₄Dy^III₅ and Mn^III₄Dy^III₃ clusters with unprecedented metal topologies and stoichiometries; both compounds exhibit out-of-phase signals indicative of the slow magnetization relaxation of a single-molecule magnet.