Dinuclear Lanthanide(III) Complexes by Metal-Ion-Assisted Hydration of Di-2-pyridyl Ketone Azine

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• 作者：Nikolaos C. Anastasiadis ; Carlos M. Granadeiro ; Nikolaos Klouras ; Lu铆s Cunha-Silva ; Catherine P. Raptopoulou ; Vassilis Psycharis ; Vlasoula Bekiari ; Salete S. Balula ; Albert Escuer ; Spyros P. Perlepes
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：April 15, 2013
• 年：2013
• 卷：52
• 期：8
• 页码：4145-4147
• 全文大小：215K
• 年卷期：v.52,no.8(April 15, 2013)
• ISSN：1520-510X

文摘

The initial employment of di-2-pyridyl ketone azine in 4f metal chemistry has led to a unique ligand transformation; the resulting anionic ligand is able to bridge two Ln^III ions, affording neutral and cationic dinuclear complexes with interesting properties.