Molecular Nanoscale Magnetic Refrigerants: A Ferrimagnetic {CuII15GdIII7} Cagelike Cluster from the Use of Pyridine-2,6-dimethanol

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• 作者：Despina Dermitzaki ; Giulia Lorusso ; Catherine P. Raptopoulou ; Vassilis Psycharis ; Albert Escuer ; Marco Evangelisti ; Spyros P. Perlepes ; Theocharis C. Stamatatos
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：September 16, 2013
• 年：2013
• 卷：52
• 期：18
• 页码：10235-10237
• 全文大小：219K
• 年卷期：v.52,no.18(September 16, 2013)
• ISSN：1520-510X

文摘

The employment of pyridine-2,6-dimethanol in 3d/4f metal cluster chemistry has afforded a new {Cu^II₁₅Gd^III₇} cagelike molecule with a beautiful structure built by fused triangular subunits; the compound exhibits an overall ferrimagnetic behavior with an appreciable ground-state spin value and shows promise as a low-temperature magnetic refrigerant.