Approach to the Tricyclic Core of the Tigliane鈥揇aphnane Diterpenes. Concerning the Utility of Transannular Aldol Additions

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• 作者：Arthur J. Catino ; Alexandra Sherlock ; Peyton Shieh ; Joseph S. Wzorek ; David A. Evans
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：July 5, 2013
• 年：2013
• 卷：15
• 期：13
• 页码：3330-3333
• 全文大小：282K
• 年卷期：v.15,no.13(July 5, 2013)
• ISSN：1523-7052

文摘

Two transannular (TA) aldol reactions were used to assemble the tricyclic carbon skeleton found in the tigliane and daphnane classes of diterpene natural products.