Chelating Ligand Conformation Driving the Hypoxanthine Metal Binding Patterns

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• 作者：Dheerendra K. Patel ; Duane Choquesillo-Lazarte ; Alicia Dom铆nguez-Mart铆n ; M. Pilar Brandi-Blanco ; Josefa Mar铆a Gonz谩lez-P茅rez ; Alfonso Casti帽eiras ; Juan Nicl贸s-Guti茅rrez
• 刊名：Inorganic Chemistry
• 出版年：2011
• 出版时间：November 7, 2011
• 年：2011
• 卷：50
• 期：21
• 页码：10549-10551
• 全文大小：717K
• 年卷期：v.50,no.21(November 7, 2011)
• ISSN：1520-510X

文摘

The X-ray diffraction structural results of 23 ternary compounds, type Mp>IIp>(iminodiacetate-like)(hypoxanthine) [M = Co, Ni, Cu, or Zn], show that the iminodiacetate moiety conformation (mer-NO₂ or fac-NO₂) is able to drive the M-hypoxanthine binding patterns displaying the M鈥揘9 or M鈥揘3 bond, cooperating with a N9鈥揌路路路O intramolecular interaction, respectively.