Ferrocene in Conjugation with a Fischer Carbene: Synthesis, NLO, and Electrochemical Behavior of a Novel Organometallic Push-Pull System
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- 作者：K. N. Jayaprakash ; Paresh C. Ray ; Isao Matsuoka ; Mohan M. Bhadbhade ; Vedavathi G. Puranik ; Pushpendu K. Das ; Hiroshi Nishihara ; and Amitabha Sarkar
- 刊名：Organometallics
- 出版年：1999
- 出版时间：September 13, 1999
- 年：1999
- 卷：18
- 期：19
- 页码：3851 - 3858
- 全文大小：141K
- 年卷期：v.18,no.19(September 13, 1999)
- ISSN：1520-6041
文摘
Using an iterative sequence of Wittig olefination, reduction, oxidation, and condensationof an active methylene group to carbonyl, it was possible to prepare a series of organometallicpush-pull molecules [(CO)5M=C(OCH3)(-CH=CH-)n(C5H4)Fe(C5H5), M = W, Cr, n = 1-4]in which ferrocene is the donor element and a Fisher carbene moeity is the acceptor group.The molecular first hyperpolarizability 
was determined by hyper-Rayleigh scatteringexperiments. The values ranged from 110 × 10-30 to 2420 × 10-30 esu in acetonitrile, andthey are among the highest reported for organometallic molecules so far. Electrochemicalmeasurements are consistent with the push-pull nature of these compounds.
was determined by hyper-Rayleigh scatteringexperiments. The values ranged from 110 × 10-30 to 2420 × 10-30 esu in acetonitrile, andthey are among the highest reported for organometallic molecules so far. Electrochemicalmeasurements are consistent with the push-pull nature of these compounds.