Elegant Approach to the Synthesis of a Unique Heteroleptic Cyclometalated Iridium(III)-Polyoxometalate Conjugate
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- 作者：Benjamin Matt ; Jamal Moussa ; Lise-Marie Chamoreau ; Carlos Afonso ; Anna Proust ; Hani Amouri ; Guillaume Izzet
- 刊名：Organometallics
- 出版年：2012
- 出版时间：January 9, 2012
- 年：2012
- 卷：31
- 期：1
- 页码：35-38
- 全文大小：253K
- 年卷期：v.31,no.1(January 9, 2012)
- ISSN：1520-6041
文摘
A novel heteroleptic cyclometalated iridium(III) complex with one picolinic acid derivative bearing a pendant terminal alkynyl tether has been prepared following a new synthetic route. This pendant alkynyl tether can be further engaged in palladium C鈥揅 coupling reactions, allowing its grafting to a Keggin-type polyoxometalate and thus providing a unique iridio-POM conjugate.