Selective Visible-Light-Driven CO2 Reduction on a p-Type Dye-Sensitized NiO Photocathode

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• 作者：Andreas Bachmeier ; Samuel Hall ; Stephen W. Ragsdale ; Fraser A. Armstrong
• 刊名：Journal of the American Chemical Society
• 出版年：2014
• 出版时间：October 1, 2014
• 年：2014
• 卷：136
• 期：39
• 页码：13518-13521
• 全文大小：342K
• ISSN：1520-5126

文摘

We present a photocathode assembly for the visible-light-driven selective reduction of CO₂ to CO at potentials below the thermodynamic equilibrium in the dark. The photoelectrode comprises a porous p-type semiconducting NiO electrode modified with the visible-light-responsive organic dye P1 and the reversible CO₂ cycling enzyme carbon monoxide dehydrogenase. The direct electrochemistry of the enzymatic electrocatalyst on NiO shows that in the dark the electrocatalytic behavior is rectified toward CO oxidation, with the reactivity being governed by the carrier availability at the semiconductor鈥揷atalyst interface.