Biomass Char Direct Chemical Looping Gasification Using NiO-Modified Iron Ore as an Oxygen Carrier

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• 作者：Zhen Huang ; Fang He ; Yipeng Feng ; Kun Zhao ; Anqing Zheng ; Sheng Chang ; Guoqiang Wei ; Zengli Zhao ; Haibin Li
• 刊名：Energy & Fuels
• 出版年：2014
• 出版时间：January 16, 2014
• 年：2014
• 卷：28
• 期：1
• 页码：183-191
• 全文大小：509K
• ISSN：1520-5029

文摘

Chemical looping gasification (CLG) is considered as a novel gasification technology because gas-phase oxygen of the gasifying medium can be replaced by lattice oxygen of the oxygen carrier. The gasifying mediums (e.g., pure O₂ and steam) used as the oxygen source can apparently improve the char conversion in traditionally biomass gasification. Similarly, the objective of this study is to investigate char CLG with the oxygen carrier as an individual oxygen source. A NiO-modified iron ore oxygen carrier was prepared by the impregnation method coupled with ultrasonic treatment. The characteristics of the oxygen carrier were analyzed by an X-ray diffractometer (XRD) and H₂ temperature-programmed reduction (H₂-TPR). The formation of spinel-type nickel iron oxide NiFe₂O₄ can evidently enhance the reactivity of the oxygen carrier. The reduction of the oxygen carrier by biomass char was investigated using thermogravimetric analysis (TGA) together with a fixed-bed reactor under an inert atmosphere. TGA tests show that the reactivity of the oxygen carrier increased with the increase of NiO loading. An optimal mass ratio of char/oxygen carrier is determined at 4:6 with the aim of obtaining a maximum reaction rate. The presence of spinel-type nickel iron oxide NiFe₂O₄ apparently improved the reaction rate of char gasification. The fixed-bed gasification results show that CO was generated faster than other components because carbon was partially oxidized and H₂ was quickly consumed by the lattice oxygen [O] of the oxygen carrier. A relatively high carbon conversion of 55.56% was obtained in the char CLG, in comparison to that of char pyrolysis (5.52%). The lattice oxygen [O] of the oxygen carrier was fully consumed by biomass char. Moreover, biomass char was catalytically pyrolyzed becausee the deep reduction products (metallic iron and nickel) can act as catalysts for char pyrolysis. XRD analysis shows that the oxygen carrier was deeply reduced into Fe (Ni) alloy and Fe₃C species during the reduction stage of char CLG. However, the regenerated oxygen carrier after oxidation can be recycled for char CLG on the basis of XRD and scanning electron microscopy (SEM) analyses.