Highly Diastereoselective Nucleophilic Addition to Myrtenal. Straightforward Synthesis of an Enantiopure Scorpionate Ligand

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• 作者：Antonio Otero ; Juan Fern&aacute ; ndez-Baeza ; Antonio Antiñ ; olo ; Juan Tejeda ; Agustí ; n Lara-S&aacute ; nchez ; Luis F. S&aacute ; nchez-Barba ; Margarita S&aacute ; nchez-Molina ; Sonia Franco ; Maria
• 刊名：Inorganic Chemistry
• 出版年：2007
• 出版时间：October 15, 2007
• 年：2007
• 卷：46
• 期：21
• 页码：8475 - 8477
• 全文大小：98K
• 年卷期：v.46,no.21(October 15, 2007)
• ISSN：1520-510X

文摘

The work described here represents the first example in which anefficient and highly diastereoselective nucleophilic 1,2-addition ofan organolithium reagent has been performed on a carbonylicprostereogenic center to give an enantiopure scorpionate ligandin only one step.