Can Faradaic Processes in Residual Iron Catalyst Help Overcome Intrinsic EDLC Limits of Carbon Nanotubes?

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• 作者：Robert K. Emmett ; Mehmet Karakaya ; Ramakrishna Podila ; Margarita R. Arcila-Velez ; Jingyi Zhu ; Apparao M. Rao ; Mark E. Roberts
• 刊名：Journal of Physical Chemistry C
• 出版年：2014
• 出版时间：November 20, 2014
• 年：2014
• 卷：118
• 期：46
• 页码：26498-26503
• 全文大小：376K
• ISSN：1932-7455

文摘

The promise of multiwalled carbon nanotubes (MWNTs) for supercapacitor electrodes remains unfulfilled due to their poor energy density, which is limited by their redox inactivity. Here, we show a simple, alternative path to achieve Faradaic charge storage by harnessing intrinsic heterogeneity (e.g., Fe catalyst) of as-synthesized MWNTs, obviating the challenges of combining disparate materials in hybrid composite electrodes. In acidic solutions, MWNTs are ruptured by voltammetric cycling beyond the electrolysis limit, thereby exposing residual catalyst nanoparticles. The addition of Faradaic charge storage associated with the Fe²⁺/Fe³⁺ transition, results in a 4-fold increase in peak capacitance of MWNT electrodes (290 F/g) compared to purified MWNT electrodes (70 F/g), along with a 60% increase in charge capacity.