Influence of Coordinating and Non-Coordinating Anions and of a Methoxy Substituent on the Formation of Copper-Based Coordination Assemblies
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- 作者：Jinkui Tang ; José ; Sá ; nchez Costa ; Andrej Pevec ; Bojan Kozlevč ; ar ; Chiara Massera ; Olivier Roubeau ; Ilpo Mutikainen ; Urho Turpeinen ; Patrick Gamez ; Jan Reedijk
- 刊名：Crystal Growth & Design
- 出版年：2008
- 出版时间：March 2008
- 年：2008
- 卷：8
- 期：3
- 页码：1005 - 1012
- 全文大小：1419K
- 年卷期：v.8,no.3(March 2008)
- ISSN：1528-7505
文摘
A series of copper(II) complexes with pyridine-phenol-based N,O/donor ligands has been synthesized and structurally characterized. Slight variations of one of the building blocks (namely, the ligand or the counterion) lead to drastic changes in the nature of the resulting coordination assemblies. Indeed, depending on the anions involved and on a minor modification of the ligand, a dinuclear, a one-dimensional chain, or two cubane copper structures are obtained. The magnetic properties of all polynuclear copper(II) compounds have been investigated, which show that the different clusters exhibit antiferromagnetic interactions.