Synthesis of 2,4,5-Trisubstituted 3-Fluorofurans via Sequential Iodocyclization and Cross-Coupling of gem-Difluorohomopropargyl Alcohols

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• 作者：Satoru Arimitsu ; Jesse M. Jacobsen ; Gerald B. Hammond
• 刊名：Journal of Organic Chemistry
• 出版年：2008
• 出版时间：April 4, 2008
• 年：2008
• 卷：73
• 期：7
• 页码：2886 - 2889
• 全文大小：74K
• 年卷期：v.73,no.7(April 4, 2008)
• ISSN：1520-6904

文摘

The acid treatment of a ruthenabenzene yielded an unusualdialdehyde. Interestingly, this dialdehyde has notable anti-oxidative properties and resists even nitric acid. This stabilityis confirmed by chemical and electrochemical experiments.In addition, a stable cyclic anhydride is synthesized fromthe dialdehyde via an environmentally friendly electrochemical method.