Synthesis of Stachybotrin C and All of Its Stereoisomers: Structure Revision

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• 作者：Maiwenn Jacolot ; Mickael Jean ; Naresh Tumma ; Arnaud Bondon ; Srivari Chandrasekhar ; Pierre van de Weghe
• 刊名：The Journal of Organic Chemistry
• 出版年：2013
• 出版时间：July 19, 2013
• 年：2013
• 卷：78
• 期：14
• 页码：7169-7175
• 全文大小：376K
• 年卷期：v.78,no.14(July 19, 2013)
• ISSN：1520-6904

文摘

We disclose the first total synthesis of stachybotrin C, a potent neuroprotective natural compound. All of the four stereoisomers have been prepared and fully characterized with the aim to attribute the absolute configuration of the two adjacent stereocenters of the stachybotrin C.