Access to Aryl Mellitic Acid Esters through a Surprising Oxidative Esterification Reaction
详细信息 查看全文
- 作者：Margarita R. Geraskina ; Mark J. Juetten ; Arthur H. Winter
- 刊名：Journal of Organic Chemistry
- 出版年：2014
- 出版时间：June 6, 2014
- 年：2014
- 卷：79
- 期：11
- 页码：5334-5337
- 全文大小：262K
- 年卷期：v.79,no.11(June 6, 2014)
- ISSN：1520-6904
文摘
A serendipitously discovered oxidative esterification reaction of cyclohexane hexacarboxylic acid with phosphorus pentachloride and phenols provides one-pot access to previously unknown aryl mellitic acid esters. The reaction features a solvent-free digestion and chromatography-free purifications and demonstrates the possibility of cyclohexane-to-benzene conversions under relatively mild, metal-free conditions.