Asymmetric Transformations under Iridium/Chiral Diene Catalysis

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• 作者：Midori Nagamoto ; Takahiro Nishimura
• 刊名：ACS Catalysis
• 出版年：2017
• 出版时间：January 6, 2017
• 年：2017
• 卷：7
• 期：1
• 页码：833-847
• 全文大小：1467K
• ISSN：2155-5435

文摘

Chelating chiral dienes have become steering ligands for iridium in several types of asymmetric reactions. Some effective examples realized only by use of chiral diene ligands instead of conventional ligands based on phosphine and nitrogen have appeared in the iridium-catalyzed processes. In particular, it should be noted that Ir/chiral diene catalysts allow enantioselective reactions involving C–H bond activation. In this Perspective, recent progress in asymmetric reactions catalyzed by Ir/chiral diene complexes is summarized.