Effect of Relative Humidity on OH Uptake by Surfaces of Atmospheric Importance

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• 作者：Jong-Ho Park ; Andrey V. Ivanov ; Mario J. Molina
• 刊名：Journal of Physical Chemistry A
• 出版年：2008
• 出版时间：July 31, 2008
• 年：2008
• 卷：112
• 期：30
• 页码：6968-6977
• 全文大小：320K
• 年卷期：v.112,no.30(July 31, 2008)
• ISSN：1520-5215

文摘

An experimental study of the dependence of the OH uptake coefficient γ_OH over a relative humidity of 0−48% was carried out at 100 Torr and room temperature, using a differential bead-filled flow tube coupled to a high-pressure chemical ionization mass spectrometer. Various organic (paraffin wax, pyrene, glutaric acid, and soot) and inorganic (NaCl, KCl, MgCl₂, CaCl₂, Na₂SO₄, and sea salt) surfaces served as proxies for tropospheric aerosols. A virtual cylindrical flow tube approximation and a surface coating dilution technique were successfully employed in the study, which included measurements of high radical uptake with an initial probability of near unity. For inorganic salts, the effect of water vapor, enhancement or inhibition of γ_OH, was found to be dependent on the blocking of anions and changes in surface pH. Although OH uptake by NaCl, the major component of sea-salt aerosols, is weakly dependent on water vapor, it is enhanced by a factor of ∼2 for MgCl₂ and determines the net relative humidity dependence of the radical uptake on sea salt, which is enhanced by a factor of ∼4. For the organic surfaces studied, the enhancement effect of a factor 4 was also observed only for a hydrophilic organic surface, namely, glutaric acid. Results of the uptake studies suggest that the effect of relative humidity is important and should be accounted for in atmospheric modeling of tropospheric aerosol chemistry.