Unusual Electrochemical Properties of the Electropolymerized Thin Layer Based on a s-Tetrazine-Triphenylamine Monomer

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• 作者：Sandra Pluczyk ; Pawel Zassowski ; Cassandre Quinton ; Pierre Audebert ; Valérie Alain-Rizzo ; Mieczyslaw Lapkowski
• 刊名：Journal of Physical Chemistry C
• 出版年：2016
• 出版时间：March 3, 2016
• 年：2016
• 卷：120
• 期：8
• 页码：4382-4391
• 全文大小：591K
• ISSN：1932-7455

文摘

In this work the electrochemical and spectroelectrochemical characterization of a s-tetrazine-triphenylamine derivative with a donor–acceptor–donor-type structure is reported, which in addition undergoes electrochemical polymerization. The investigations of the polymerized layers have revealed unusual characteristics. Thin polymeric film exhibits charge-trapping properties with great storage and memory effect. Moreover, the polymer displays reversible switching of fluorescence in oxidation mode and emission of light during reduction.